Ultrasound-assisted electrodeposition synthesis of nZVI-Pd/AC toward reductive degradation of methylene blue

Environmental Science and Pollution Research - A novel composite (nZVI/Pd-AC) was prepared by loading nanoscale zero-valent iron (nZVI) and Pd on activated carbon (AC) electrode under...     

An asymmetric analysis of the impacts of energy use on carbon dioxide emissions in the G7 countries

Environmental Science and Pollution Research - The foremost theme of the paper is to explore the asymmetric/symmetric impact of energy consumption on the carbon dioxide emission of G7 countries...     

Effects of intercropping with floricultural accumulator plants on cadmium accumulation in grapevine

Environmental Science and Pollution Research - Grapevine (Vitis vinifera L.) intercropping with floricultural cadmium (Cd) accumulator plants (Helianthus annuus L., Cosmos sulphureus Cav., Cosmos...     

神农架大九湖亚高山泥炭湿地甲烷通量变化特征及其与产甲烷菌群落组成的关系

2018年12月～2019年11月,采用涡度相关法和高通量测序技术,以湖北省神农架大九湖亚高山泥炭湿地为研究对象,对甲烷(CH4)通量以及产甲烷菌群落组成进行相关研究.结果 及分析表明:大九湖泥炭湿地研究期间表现为CH4的源,CH4总排放量为9333.26 mg· m-2,CH4日平均排放通量为18.50 nmol·m-2·s-1,冬、春、夏、秋四季的CH4平均排放通量分别为6.46、4.62、36.81、25.92 nmol·m-2·s-1,存在明显的季节变化;研究区产甲烷菌优势菌群为Methanoregula(66.73％)和Methanocella(21.99％);对样本中产甲烷菌的Shannon指数进行双因素方差分析发现,同一季节不同深度的样本中产甲烷菌多样性存在显著差异,随着深度的增加,产甲烷菌的多样性指数呈下降趋势;同一深度不同季节的样本中产甲烷菌多样性存在显著差异;夏季产甲烷菌群落组成与CH4排放通量为强正相关关系,春季产甲烷菌群落组成与CH4排放通量为强负相关关系,Methanothermus与CH4排放通量为显著正相关关系,Methanolinea与CH4排放通量为显著负相关关系.     

羟胺强化Fenton反应降解水中氯酚

针对传统Fenton体系Fe（Ⅲ）累积和pH适用范围过窄等缺点，采用羟胺（HA）强化的HA-Fenton体系，以对氯苯酚（4-CP）为目标污染物进行降解实验，考察了Fe（Ⅱ）投加量、H2O2投加量、HA投加量和溶液pH等工艺条件对4-CP去除率的影响。实验结果表明：HA-Fenton体系适用于酸性和弱酸性条件，最佳pH范围为3.0~4.0；在溶液pH为3.0、Fe（Ⅱ）投加量为5.0 μmol/L、H2O2投加量为0.4 mmol/L、HA投加量为0.20 mmol/L的最适条件下，反应10 min， 4-CP去除率达64.25 %。     

液液萃取-气相色谱法测定水质可萃取性石油烃C10~C40

建立了以环己烷为萃取剂、气相色谱法(氢火焰离子化检测器,FID)测定水质样品中可萃取性石油烃(C_(10)～C_(40))的分析方法。以正构烷烃混合标准溶液为定性和定量校准标准,以色谱峰面积总和与混合标准溶液总浓度建立校准曲线进行外标法定量。方法检出限为0.01 mg/L,经验证方法精密度和准确度良好。同时,分别以气相色谱法和红外光度法测定了地表水、污水处理厂出水、海水和化工废水等实际样品,对比实验结果表明,在可萃取性石油烃C_(10)～C_(40)的碳数范围内,气相色谱法的测试结果与红外光度法无明显差异,有较好的可比性。     

MoS_2/Bi_2S_3异质结光催化剂的制备及其光催化性能

以五水硝酸铋为铋源、钼酸钠为钼源、硫脲为硫源,采用简单的一步水热法合成了MoS_2/Bi_2S_3异质结光催化剂,采用XRD,SEM,TEM,BET,UV-Vis DRS技术对其进行了表征。表征结果显示,MoS_2纳米片在Bi_2S_3微棒表面生长,增加了比表面积和活性位点,并形成异质结构,促进了光生载流子的迁移,抑制了电子-空穴对的再复合。实验结果表明:钼酸钠与五水硝酸铋的质量比为1∶2时制备的复合光催化剂性能最好,反应180min时对亚甲基蓝的去除率可达96.4%,明显高于MoS_2和Bi_2S_3,且具有较高的稳定性;该催化剂对罗丹明B、甲基橙和4-硝基苯酚的去除率分别为97.1%、93.1%和90.5%,表明其对污染物具有普适性。     

Effect of ventilation rate on air cleanliness and energy consumption in operation rooms at rest

The interrelationships between ventilation rate, indoor air quality, and energy consumption in operation rooms at rest are yet to be understood. We investigate the effect of ventilation rate on indoor air quality indices and energy consumption in ORs at rest. The study investigates the air temperature, relative humidity, concentrations of carbon dioxide, particulate matter (PM), and airborne bacteria at different ventilation rates in operation rooms at rest of a medical center. The energy consumption and cost analysis of the heating, ventilating, and air conditioning (HVAC) system in the operation rooms at rest were also evaluated for all ventilation rates. No air-conditioned operation rooms had very highest PM and airborne bacterial concentrations in the operation areas. The bacterial concentration in the operation areas with 6–30 air changes per hour (ACH) was below the suggested level set by the United Kingdom (UK) for an empty operation room. A 70% of reduction in annual energy cost by reducing the ventilation rate from 30 to 6 ACH was found in the operation rooms at rest. Maintenance of operation rooms at ventilation rate of 6 ACH could save considerable amounts of energy and achieve the goal of air cleanliness.     

长江经济带城市黑臭水体空间分布格局及影响因子

满足人民群众对优美生态环境的需要是建设美丽中国的核心要务,而城市黑臭水体是危害城市居民生产生活和身心健康的重要污染源。该研究以长江经济带城市黑臭水体为研究对象,综合运用GIS技术与地理探测器方法,识别其空间特征及分布规律,探究不同因子对黑臭水体空间格局的影响差异并提出整治建议。研究表明:(1)长江经济带城市黑臭水体空间分布呈凝聚型分布,且空间分异较为明显。核密度表现为多单核中心独立、次级中心带状及零星分布特征。(2)黑臭水体重心位置处在湖北和湖南省中部城市区域,其系统具有明显无标度区,分形特征显著,空间结构复杂性强。(3)不同类型黑臭水体均属正值空间相关性,呈"上游冷、中下游热"的冷热点区差异格局。(4)空间结构的地理探测影响因素在全域范围内贡献力不明显,分区影响因子匹配凸出。工业废水排放量、居民生活用水量、排水管道长度等是显著影响因素。建议应从严守生态规矩、建立黑臭水体治理体制机制、完善识别评定技术标准体系、创新实践整治、丰富理论研究等方面推进城市黑臭水体治理和消除。